Till death do us part… Forever chemicals!
Lesley Mukwada
Director at The Chemistry Solutions Company (M.Sc) | Global Cleantech Innovation Programme - UNIDO Mentor in South Africa
"Forever chemicals" is a term used to describe per- and poly-fluoroalkyl substances (PFAS), a group of synthetic chemicals that are resistant to degradation. They are called "forever chemicals" because they persist in the environment for a very long time. PFAS have been used in various industrial and consumer products due to their water and grease resistance properties. However, they have been linked to potential health and environmental risks. Efforts are being made to regulate and reduce their usage to minimize their impact on human health and the environment.
The origins of PFAS can be traced back to the 1930s when researchers began working on fluorinated compounds. The discovery of the first perfluorinated compounds dates back to the 1940s. Some of the early PFAS compounds, like perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS), were later used in a wide range of industrial and consumer applications due to their stability and resistance to degradation.
Manufacturing and use of PFAS increased significantly during the latter half of the 20th century, with their incorporation into various products such as non-stick cookware, stain-resistant fabrics, firefighting foams, and more. These compounds' widespread use led to their eventual detection in the environment, raising concerns about their persistence and potential health and environmental impacts. Growing awareness of the potential risks associated with PFAS has led to increased research, regulatory scrutiny, and efforts to find safer alternatives.
Health effects
You may be wondering, how these forever chemicals affect your health. PFAS exposure has been associated with several potential health effects in humans, although research in some areas is still ongoing. Some of the health impacts of PFAS exposure include:
1. Increased Cholesterol Levels: Studies have shown that exposure to certain PFAS compounds can lead to elevated levels of cholesterol in the blood, which may increase the risk of cardiovascular diseases.
2. Immune System Effects: PFAS exposure has been linked to alterations in the immune system, potentially leading to reduced vaccine effectiveness and increased susceptibility to infections.
3. Liver Damage: Some PFAS compounds have been associated with liver toxicity, including liver enzyme elevation and non-alcoholic fatty liver disease (NAFLD).
4. Thyroid Hormone Disruption: Certain PFAS have been shown to interfere with thyroid hormone levels, potentially leading to thyroid dysfunction and related health issues.
5. Reproductive and Developmental Effects: PFAS exposure has been linked to adverse effects on reproductive health, including decreased fertility, delayed puberty, and alterations in hormone levels. There are also concerns about potential developmental effects on unborn children.
6. Cancer: Some epidemiological studies have suggested potential links between PFAS exposure and certain cancers, but more research is needed to establish conclusive evidence.
7. Kidney Function: Certain PFAS compounds have been associated with reduced kidney function and kidney disease.
It's important to note that the health impacts of PFAS can vary depending on the specific chemical compounds, levels of exposure, and individual susceptibility. PFAS exposure can occur through various routes, including ingestion of contaminated food and water, inhalation of airborne particles, and contact with PFAS-containing products.
Given the potential health risks, regulatory agencies and researchers are actively investigating PFAS exposure and working on strategies to reduce human exposure to these chemicals.
What makes them forever chemicals?
PFAS have unique chemical properties, particularly the strong carbon-fluorine bond, which makes them highly stable and resistant to degradation in the environment. This stability is the reason behind their persistence, leading to the nickname "forever chemicals."
The key characteristics of the chemistry of PFAS are:
1. Carbon-Fluorine Bond: PFAS molecules consist of a carbon backbone with fluorine atoms attached to them. The carbon-fluorine bond is one of the strongest chemical bonds known, making PFAS highly resistant to breakdown by heat, light, or microbial action.
2. Hydrophobic Nature: PFAS are hydrophobic, meaning they repel water. This property makes them useful in various applications, such as water-resistant coatings and stain repellents.
3. Oleophobic Nature: PFAS are also oleophobic, meaning they repel oils and fats. This property is valuable in applications like non-stick cookware and grease-resistant packaging.
4. Low Surface Tension: PFAS have a low surface tension, allowing them to spread easily over surfaces and form thin, uniform coatings.
5. Bioaccumulation: Due to their stability, PFAS can accumulate in living organisms over time, leading to potential health and environmental concerns.
6. Many Variants: The PFAS group includes a wide range of chemical compounds with varying carbon chain lengths and functional groups, resulting in diverse properties and applications.
The chemistry of PFAS has contributed to their widespread use in various industrial and consumer products. However, it has also raised concerns about their potential persistence, environmental contamination, and adverse health effects. As a result, efforts are being made to understand their behavior, regulate their use, and develop safer alternatives.
Where do you find forever chemicals?
?Forever chemicals have been used in various industrial and consumer applications due to their unique properties. Some common applications include:
1. Water and Stain Resistance: PFAS are used in fabric treatments, carpets, upholstery, and outdoor clothing to provide water and stain resistance.
2. Non-Stick Coatings: PFAS have been used in non-stick cookware, such as Teflon-coated pans.
3. Firefighting Foam: Certain PFAS compounds were historically used in firefighting foams to suppress flammable liquid fires.
4. Electronics: PFAS have been used in electronics for their electrical insulation properties.
5. Food Packaging: Some PFAS have been used in food packaging materials to prevent grease and moisture penetration.
6. Aerospace and Automotive Industries: PFAS are used in aerospace and automotive applications for their fire resistance and lubricating properties.
7. Textiles and Leather: PFAS are utilized in the textile and leather industries to provide water and oil repellency in products like shoes, handbags, and outdoor gear.
8. Coatings and Sealants: PFAS can be found in coatings and sealants for various surfaces, including concrete, metal, and wood, to enhance durability and weather resistance.
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9. Cleaning Products: Some cleaning products, like stain repellents and household cleaners, may contain PFAS to improve their effectiveness.
10. Cosmetics and Personal Care: Certain cosmetics and personal care products may contain PFAS to provide water resistance or to enhance texture and glide.
11. Oil and Gas Industries: PFAS are used in the oil and gas industries as additives to enhance drilling and production operations.
12. Medical Devices: Some medical devices and equipment may contain PFAS to provide lubrication and reduce friction.
13. Photolithography: In the semiconductor industry, PFAS are used in photolithography processes to enhance photoresist performance.
It's important to reiterate that while PFAS have been widely used in various applications, there is increasing concern about their potential health and environmental effects. As a result, regulatory agencies and industries are working to find safer alternatives and restrict the use of PFAS in certain products and processes.
Testing of forever chemicals
Testing for forever chemicals, specifically per- and poly-fluoroalkyl substances (PFAS), typically involves specialized laboratory analysis. Various samples can be used to detect forever chemicals and these include:
1. Water: Collect samples of water from the source of interest, such as groundwater, surface water, or drinking water sources.
2. Soil: If there is a concern about PFAS contamination in soil, collect soil samples from the affected area.
3. Blood: In some cases, blood testing may be conducted on individuals to determine their exposure to PFAS.
4. Air: For certain PFAS, air sampling may be necessary to assess the presence of airborne particles.
PFAS testing is normally done through laboratory analysis: Send the collected samples to a certified laboratory that specializes in PFAS testing. They will use advanced analytical techniques, like liquid chromatography-mass spectrometry (LC-MS) or gas chromatography-mass spectrometry (GC-MS), to detect and quantify the levels of various PFAS compounds in the samples.
It's important to note that PFAS testing requires specialized equipment and expertise. If you suspect PFAS contamination in your environment, it's best to consult with environmental or health authorities to conduct the testing properly.
How do we get rid of forever chemicals?
Treating "forever chemicals," such as per- and poly-fluoroalkyl substances (PFAS), can be challenging due to their resistance to degradation. However, there are some methods being researched and implemented to mitigate their impact on the environment and human health:
1. Source Control: Identify and eliminate sources of PFAS contamination to prevent further spread into the environment.
2. Water Treatment: Advanced water treatment technologies, such as activated carbon filtration, ion exchange, and high-pressure membranes, can help remove PFAS from drinking water and wastewater.
3. Soil Remediation: Various soil remediation techniques, such as soil washing, soil vapor extraction, and bioremediation, are being explored to remove or reduce PFAS from contaminated soil.
4. Incineration: High-temperature incineration can break down some PFAS compounds, but this method must be carefully managed to prevent the release of harmful by-products.
5. Research and Innovation: Continued research is essential to develop more effective and sustainable methods to treat and remove PFAS from different environments.
6. Policy and Regulation: Implementing strict regulations and policies to control the use and disposal of PFAS can help prevent further contamination and encourage safer alternatives.
It's important to note that treating PFAS is a complex task, and the effectiveness of different methods may vary depending on the specific compounds and environmental conditions. As research progresses, better solutions may emerge to address the challenges posed by forever chemicals.
What to do if you have been exposed to forever chemicals?
Removing "forever chemicals," such as per- and poly-fluoroalkyl substances (PFAS), from the human body is challenging since these substances are persistent and can accumulate over time. Currently, there are no known methods for complete elimination of PFAS from the human body. However, here are some general suggestions to reduce exposure and potential health risks:
1. Avoid Exposure: Minimize exposure to PFAS by avoiding products treated with PFAS, using non-stick cookware, and staying away from contaminated environments.
2. Healthy Diet: Some studies suggest that a diet rich in antioxidants and nutrients may support the body's natural detoxification processes. Including foods like fruits, vegetables, and whole grains in your diet may be beneficial.
3. Hydration: Staying well-hydrated can help support the body's natural detoxification mechanisms.
4. Consult a Healthcare Professional: If you suspect PFAS exposure or experience health issues related to PFAS, consult a healthcare professional for appropriate evaluation and guidance.
It's important to note that research on PFAS and their effects is ongoing, and medical advice may change as more information becomes available. For specific concerns about PFAS exposure or removal, it is best to seek guidance from a qualified healthcare professional who can provide personalized advice based on your individual circumstances.
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