Solar hydrogen: Barriers for charge transport in metal oxides

In theory, metal oxides are ideal photoelectrodes for the direct photoelectrochemical production of hydrogen with sunlight (PEC approach). By combining terahertz and microwave analyses, a team at Helmholtz-Zentrum Berlin has now succeeded for the first time in determining the transport properties of charge carriers in different metal oxides over a time range of nine orders of magnitude, from 100 femtoseconds to 100 microseconds. This showed how charge carriers are retained or even lost, making them unavailable for the production of hydrogen. These effects could be reduced in the first materials, leading to better photoelectrodes.

In the future, climate-neutral #hydrogen will play an important role as a fuel and raw material. Hydrogen is produced by electrolysis of water, either using an indirect approach in which an external energy source (solar panel or wind turbine) supplies the electrolysis cell with voltage, or using a direct approach: a photoelectrochemical cell in which the photoelectrode itself supplies the electrical energy for electrolysis (PEC cell). This direct approach would have some advantages, but is not yet competitive.

So far, this is mainly due to a lack of good photoelectrodes. Metal oxides are considered suitable in principle; they are inexpensive, non-toxic, stable in aqueous solution and also often possess catalytic properties that can accelerate the desired chemical reaction. And sunlight releases charge carriers in metal oxides, thus generating an electrical voltage. But compared to doped semiconductors such as silicon, these charge carriers are not very mobile, they are rather slow, or immediately settle back into the lattice and localise. This is due to various mechanisms on different time and length scales which are still poorly understood.

In the femtosecond laser laboratory at HZB, the team led by Dr. Dennis Friedrich and Dr. Hannes Hempel has now investigated in detail for the first time what limits the conductivity of metal oxides: "We wanted to find out how strongly charge carriers are localised and how this reduces their mobility at different times," says Dr. Markus Schleuning , first author of the study, who did his doctorate on this topic.

"First, we developed a new method to determine the diffusion lengths. The simple equation can also be applied to other classes of materials such as halide perovskites or silicon [1]," explains Hempel.

Then we found out that this does not work for certain materials, and precisely when the charge carriers are located [2]", adds Friedrich: "In the femtosecond laboratory, all samples are investigated with both a terahertz method (OPTP) and microwave spectroscopy (TRMC), both measurement methods initially provide information on the mobility and lifetime of the charge carriers - but on different time scales. The results can be very different, indicating that the carriers have been localised in the meantime. From ultrafast processes in the range of 100 femtoseconds to slower processes lasting 100 microseconds, the team was able to determine the dynamics of charge carriers in the materials. By way of comparison, extrapolated to our human perception of time, this would correspond to changes in time spans of 1 second to 31 years.

The physicists used this combination of methods to analyse ten metal oxide compounds, including Fe2O3, CuFeO2, α-SnWO4, BaSnO3 and CuBi2O4. For all materials, the mobilities were very low compared to conventional semiconductors. A heat treatment, annealing, significantly improved the mobility in BaSnO3. The best performer was the well-known bismuth vanadate (BiVO4), which shows little carrier localisation on the length scales studied. The study shows how metal oxide compounds can be characterised to identify and develop the best materials for photoelectrodes.

[1] PRX Energy (2022): Generalized Method to Extract Carrier Diffusion Length from Photoconductivity Transients: Cases of , Halide Perovskites, and Amorphous and Crystalline Silicon

Markus Schleuning, Moritz K?lbach, Fatwa Firdaus Abdi , Klaus Schwarzburg, Martin Stolterfoht , Rainer Eichberger, Roel van de Krol , Dennis Friedrich, Hannes Hempel

https://doi.org/10.1103/PRXEnergy.1.023008

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[2] Advanced Functional Materials (2023): Carrier Localization on the Nanometer-Scale limits Transport in Metal Oxide Photoabsorbers

Markus Schleuning, Moritz K?lbach, Ibbi Ahmet, Raphael Pr?g, Ronen Gottesman, René Gunder, Mengyuan Zhang, Dan Ralf Wargulski, Daniel Abou-Ras, Daniel A. Grave, Fatwa F. Abdi, Roel van de Krol, Klaus Schwarzburg, Rainer Eichberger, Dennis Friedrich, and Hannes Hempel

https://onlinelibrary.wiley.com/doi/epdf/10.1002/adfm.202300065??

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