PEEK vs PTFE
Stephen Jones
Global Sales Manager - Oil and Gas Division -Delivering a value added customer experience.
For decades, valve manufacturers and valve users have suffered from the limited availability of ball valve seat materials. PEEK and PTFE are the two go-to materials of choice. So much so, that the habitual use of these two materials has left a void in performance, both physically and financially. Advances in materials processing techniques and quality processes are now starting to create alternatives that have clear competitive advantages for ball valve performance.
Given the stringent safety and quality requirements for valve seats, the selection of PTFE and PEEK has become an easy option as they have a proven track record and are recognised across the industry. This though does not come without it’s challenges. All too often PEEK is supplied under pricing pressure, which has caused the trusted use of PEEK on specifications to suffer from many quality and poor manufacturing practices;
This is an important subject but for now, let’s consider what is good about PEEK and PTFE and where their place is and isn’t for ball valve seats.
PTFE – what is it good for, where does it struggle
- Good chemical resistance, low coefficient of friction, low moisture absorption, and high electrical resistance. but its flexibility at low temperatures is a key feature.
- PTFE mechanical properties are low compared to other polymers and is very soft and cannot be used for higher pressures.
PEEK – what is it good for, where does it struggle
- Outstanding chemical resistance, very low moisture uptake, good fire performance, excellent mechanical strength across a broad temperature range, and good dimensional stability.
- Relatively High Cost. It is very hard and difficult for valve companies to seal with.
So what is the gap?
Typically as pressure increases PTFE can no longer resist deformation well enough to perform long term, so PEEK is employed as the seat material of choice. Stepping from PTFE to PEEK causes a significant leap in price for valve seats. It also creates challenges around seal performance given that PEEK is so much harder and resistant to the slight deformation needed to seal against imperfections on the sealing face. Therefore, in a highly competitive landscape, moving to PEEK and the associated improvements in adjacent components and actuation can be the difference between winning and losing an opportunity. This is coupled with the influx of lower quality PEEK materials flooding the market, which can cause unreliable performance, prolonged testing due to quality issues and ultimately damaged brands and unplanned delays.
Is it about time to consider other materials as a potential solution?
Advanced material processing techniques are utilising physical properties of materials and creating high-performance characteristics without the problems with seal performance and extortionate price tags.
How can we address this challenge which is faced across the valve industry and what new developments are on the horizon?
Project Manager at Fluorten S.r.l.
4 年Mr. Jones thanks a lot for the nice article. Very interesting. I agree on most of the info read here but I have some questions / considerations I hope you don't mind If I share here: ? 1) In general PTFE is more flexible than peek (lower E modulus) but, from what I've seen, this might not be true around cryogenic temperatures. Down at that conditions and within the elastic field, the E modulus of PTFE is very close to PEEK. Around cryo temperatures, I've seen that in compression the yield point for PTFE is reached with a deformation of only 3%. Then, if you keep pushing, you'd obtain a partial plastic (and permanent) deformation on the insert (only partial recovery then when you release the load). With Peek in general, elastic behavior can be observed till 7-8% of deformation (not really a linear elastic behavior but we can assume mainly elastic). Then of course, machining roughness has to be considered for a good sealing with more rigid materials. ? 2)Adding either specific fillers to the virgin matrix, or working on specific parameters can allow the Peek to get a bit closer to the PTFE family (gain flexibility, reduce the hardness, reduce the necessary load, improve the friction coefficient and have less wear). ? 3) Another advantage of Peek, if processed correctly, is a lower porosity than PTFE. ?Of course this is not valid for every peek found on the market. You're absolutely right. Thank you again.