Molybdenum (and Tungsten) Titanium (and Niobium & Zirconium)
Srinivasa Rao
CSWIP 3.2.2, NACE LEVEL II, ISO 9001:2015 Certified Lead Auditor, PCN MT, PT, LEVEL II, BOSIET plus EBS with valid Offshore medical (OGUK). Panama Seaman.
Molybdenum (and Tungsten)
- Corrosion Resistance: Increases resistance to local (pitting, crevice) and general corrosion.
- High Temperature Strength: Added to martensitic steels.
- Ferrite Stabilizers: Used in austenitic alloys but balanced with austenite stabilizers.
Titanium (and Niobium & Zirconium)
- Intergranular Corrosion Resistance: Stabilizes stainless steel when low carbon control isn’t possible.
- Affinity for Carbon: Forms carbides, preventing chromium carbide formation and chromium depletion.
- Ferrite Stabilizers: Helps maintain structural stability
Chromium
- Importance: Chromium is crucial for stainless steel production.
- Minimum Requirement: At least 10.5% chromium is needed to form a protective chromium oxide layer on the steel surface.
- Protective Layer: The strength of this passive layer increases with higher chromium content.
- Structural Effect: Chromium induces the formation of ferrite within the alloy, acting as a ferrite stabilizer.
Nickel
- Corrosion Resistance: Nickel enhances general corrosion resistance.
- Formation of Austenite: Nickel promotes the formation of austenite, making it an austenite stabilizer.
- Nickel Content in Stainless Steel: Stainless steels with 8-9% nickel are fully austenitic, offering superior welding and working properties compared to ferritic stainless steels.
- Higher Nickel Content: Increasing nickel content beyond 8-9% improves both corrosion resistance (especially in acidic environments) and workability.