Molybdenum (and Tungsten) Titanium (and Niobium & Zirconium)

Molybdenum (and Tungsten)

  • Corrosion Resistance: Increases resistance to local (pitting, crevice) and general corrosion.
  • High Temperature Strength: Added to martensitic steels.
  • Ferrite Stabilizers: Used in austenitic alloys but balanced with austenite stabilizers.

Titanium (and Niobium & Zirconium)

  • Intergranular Corrosion Resistance: Stabilizes stainless steel when low carbon control isn’t possible.
  • Affinity for Carbon: Forms carbides, preventing chromium carbide formation and chromium depletion.
  • Ferrite Stabilizers: Helps maintain structural stability

Chromium

  • Importance: Chromium is crucial for stainless steel production.
  • Minimum Requirement: At least 10.5% chromium is needed to form a protective chromium oxide layer on the steel surface.
  • Protective Layer: The strength of this passive layer increases with higher chromium content.
  • Structural Effect: Chromium induces the formation of ferrite within the alloy, acting as a ferrite stabilizer.

Nickel

  • Corrosion Resistance: Nickel enhances general corrosion resistance.
  • Formation of Austenite: Nickel promotes the formation of austenite, making it an austenite stabilizer.
  • Nickel Content in Stainless Steel: Stainless steels with 8-9% nickel are fully austenitic, offering superior welding and working properties compared to ferritic stainless steels.
  • Higher Nickel Content: Increasing nickel content beyond 8-9% improves both corrosion resistance (especially in acidic environments) and workability.

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