ISOPROPYL ALCOHOL

Isopropanol

SECTION 1. Identification of the substance/mixture and of the company/undertaking

 1.1. Product identifier

Product name                                                Isopropanol

Synonyms                                                     IPA, Propan-2-ol, Propanol, sec-, Propyl alcohol, sec-, Dimethyl carbinol

INDEX number                                            603-117-00-0

EC number                                                    200-661-7

CAS number                                                  67-63-0

 1.2. Relevant identified uses of the substance or mixture and uses advised against

 Identified Uses                                                Industrial uses.

Uses Advised Against                                     No data available.

 1.3. Details of the supplier of the safety data sheet

Supplier                                                          BAC&CLARK SOM SHPK

Full address                                                    Prishtine Kosovo

E-mail                                                            [email protected]

SECTION 2. Hazards identification

 2.1. Classification of the substance or mixture Classification (EC) Regulation 1272/2008 (CLP): Hazard classification and indication:

Flam. Liq. 2 H225 Eye Irrit. 2 H319 STOT - SE 3   H336

 2.2. Label elements

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Hazard pictograms:

 Signal words:                                                  Danger

Hazard statements:

Precautionary statements:

H225                           Highly flammable liquid and vapour.

H319                           Causes serious eye irritation.

H336                           May cause drowsiness or dizziness.

P210                           Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P280                           Wear protective gloves/ protective clothing / eye protection / face protection.

P261                           Avoid breathing dust / fume / gas / mist / vapours / spray.

Isopropanol

P305+P351+P338        IF IN EYES: Rinse cautiously with water     for

several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P312                           Call a POISON CENTRE / doctor if   you feel unwell.

P403+P233                 Store in a well-ventilated place. Keep container

tightly closed.

Contains:                                                        PROPAN-2-OL

2.3. Other hazards

No data available.

SECTION 3. Composition/information on ingredients

 3.1. Substances

Contains:

 Identification

Conc. %

Classification 1272/2008 (CLP)

PROPAN-2-OL

 CAS 67-63-0

100

Flam. Liq. 2 H225, Eye Irrit. 2 H319, STOT SE 3 H336

EC 200-661-7

INDEX 603-117-00-0

 The full wording of hazard (H) phrases is given in section 16 of the sheet.

 3.2. Mixtures                                                 Information not relevant

 SECTION 4. First aid measures

 4.1. Description of first aid measures

 Eyes:                                                             Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem persists, seek medical advice.

Skin:                                                              Remove contaminated clothing. Wash immediately with plenty of water. If irritation persists, get medical advice/attention. Wash contaminated clothing before using it again.

Inhalation:                                                      Remove to open air. In the event of breathing difficulties, get medical advice/attention immediately.

Ingestion:                                                       Get medical advice/attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious person, unless authorised by a doctor.

 4.2. Most important symptoms and effects, both acute and delayed

Information not available

 4.3. Indication of any immediate medical attention and special treatment needed

Information not available

Isopropanol

SECTION 5. Firefighting measures

 5.1. Extinguishing media

Suitable Extinguishing Equipment                    Extinguishing substances are: carbon dioxide, foam, chemical powder. For

product loss or leakage that has not caught fire, water spray can be used to disperse flammable vapours and protect those trying to stem the leak.

 Unsuitable Extinguishing Equipment                Do not use jets of water. Water is not effective for putting out fires but can

be used to cool containers exposed to flames to prevent explosions.

 5.2. Special hazards arising from the substance or mixture

Excess pressure may form in containers exposed to fire at a risk of explosion. Do not breathe combustion products.

 5.3. Advice for firefighters

General Information:                                       Use jets of water to cool the containers to prevent  product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations.

 Special Protective Equipment For Fire-Fighters: Normal firefighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659)

and boots (HO specification A29 and A30) in combination with self- contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).

 SECTION 6. Accidental release measures

 6.1. Personal precautions, protective equipment and emergency procedures

Block the leakage if there is no hazard.

Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency procedures.

 Send away individuals who are not suitably equipped. Use explosion-proof equipment. Eliminate all sources of ignition (cigarettes, flames, sparks, etc.) from the leakage site.

6.2. Environmental precautions

The product must not penetrate into the sewer system or come into contact with surface water or ground water.

6.3. Methods and material for containment and cleaning up

Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the remainder with inert absorbent material.

Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13.

6.4. Reference to other sections

Any information on personal protection and disposal is given in sections 8 and 13.

SECTION 7. Handling and storage

 7.1. Precautions for safe handling

Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Vapours may catch fire and an explosion may occur; vapour accumulation is therefore to be avoided by leaving windows and doors open and ensuring good cross ventilation. Without adequate ventilation, vapours may accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic charges. When performing transfer operations involving large containers, connect to an earthing system and wear antistatic footwear. Vigorous stirring and flow through the tubes and equipment may cause the formation and accumulation of electrostatic charges. In order to avoid the risk of fires and explosions, never use compressed air when handling. Open containers with caution as they may be pressurised. Do not eat, drink or smoke during use. Avoid leakage of the product into the environment.

7.2. Conditions for safe storage, including any incompatibilities

Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Store in a well ventilated place, keep far away from sources of heat, naked flames and sparks and other sources of ignition. Keep containers away from any incompatible materials, see section 10 for details.

Storage class TRGS 510 (Germany): 3

7.3. Specific end use(s)

Information not available

SECTION 8. Exposure controls/personal protection

 8.1. Control parameters

Regulatory References:

BGR

България

МИНИСТЕРСТВО НА ТРУДА И СОЦИАЛНАТА ПОЛИТИКА МИНИСТЕРСТВО НА ЗДРАВЕОПАЗВАНЕТО НАРЕДБА No 13 от 30 декември 2003 г (4

Септември 2018г)

 CZE

?eská Republika

Na?ízení vlády ?. 246/2018 Sb. Na?ízení vlády, kterym se mění na?ízení vlády ?. 361/2007 Sb., kterym se stanoví podmínky ochrany zdraví p?i práci, ve znění pozděj?ích p?edpis?

DEU

Deutschland

TRGS 900 - Seite 1 von 69 (Fassung 29.03.2019)- Liste der Arbeitsplatzgrenzwerte und Kurzzeitwerte

DNK

Danmark

Bekendtg?relse om ?ndring af bekendtg?relse om gr?nsev?rdier for stoffer og materialer1- BEK nr 655 af 31/05/2018

ESP

Espa?a

LíMITES DE EXPOSICIóN PROFESIONAL PARA AGENTES QUíMICOS EN ESPA?A 2019 (INSST)

EST

Eesti

T??keskkonna keemiliste ohutegurite piirnormid. Vastu v?etud Vabariigi Valitsuse

18. septembri 2001. a m??rusega nr 293 (RT I 2001, 77, 460), j?ustunud 29.09.2001. Muudetud j?rgmise m??rusega (kuup?ev, number, avaldamine Riigi Teatajas, j?ustumise aeg): 11.10.2007 nr 223 (RT I 2007, 55, 369) 1.01.2008

FRA

France

Valeurs limites d'exposition professionnelle aux agents chimiques en France. ED 984 - INRS

GBR

United Kingdom

EH40/2005 Workplace exposure limits (Third edition,published 2018)

GRC

Ελλ?δα

ΕΦΗΜΕΡΙ Α ΤΗΣ ΚΥΒΕΡΝΗΣΕΩΣ - ΤΕΥΧΟΣ ΠΡΩΤΟ Αρ. Φ?λλου 152 - 21

Αυγο?στου 2018

HRV

Hrvatska

Pravilnik o za?titi radnika od izlo?enosti opasnim kemikalijama na radu, grani?nim vrijednostima izlo?enosti i biolo?kim grani?nim vrijednostima (NN 91/18)

HUN

Magyarország

A pénzügyminiszter 7/2018. (VIII. 29.) PM rendelete a munkahelyek kémiai biztonságáról szóló 25/2000. (IX. 30.) EüM SZCSM együttes rendelet módosításáról

LTU

Lietuva

LIETUVOS HIGIENOS NORMA HN 23:2011 ?CHEMINI? MED?IAG? PROFESINIO POVEIKIO RIBINIAI DYD?IAI. MATAVIMO IR POVEIKIO VERTINIMO BENDRIEJI REIKALAVIMAI. Nr. V-695/A1-272, 2018-06-12, paskelbta TAR 2018-06-15, i. k.

2018-09988

LVA

Latvija

?īmisko vielu aroda ekspozīcijas robe?vērtības (AER) darba vides gaisā 2018

NLD

Nederland

Regeling van de Staatssecretaris van Sociale Zaken en Werkgelegenheid van 13 juli 2018, 2018-0000118517 tot wijziging van de Arbeidsomstandighedenregeling in verband met de implementatie van Richtlijn 2017/164 in Bijlage XIII

NOR

Norge

Fastsatt av Arbeids- og sosialdepartementet 21. august 2018 med hjemmel i lov 17. juni 2005 nr. 62 om arbeidsmilj?, arbeidstid, stillingsvern mv. (arbeidsmilj?loven) § 1- 3, § 1-4 og § 4-5

POL

Polska

ROZPORZ?DZENIE MINISTRA RODZINY, PRACY I POLITYKI SPO?ECZNEJ z

dnia 12 czerwca 2018 r

ROU

Romania

HOT?R?RE nr. 584 din 2 august 2018 pentru modificarea Hot?rarii Guvernului nr. 1.218/2006 privind stabilirea cerin?elor minime de securitate ?i s?n?tate ?n munc? pentru asigurarea protec?iei lucr?torilor ?mpotriva riscurilor legate de prezen?a agen?ilor chimici

SVK

Slovensko

Nariadenie vlády ?. 33/2018 Z. z. Nariadenie vlády Slovenskej republiky, ktorym sa mení a dop?ňa nariadenie vlády Slovenskej republiky ?. 355/2006 Z. z. o ochrane zamestnancov pred rizikami súvisiacimi s expozíciou chemickym faktorom pri práci v znení neskor?ích predpisov

SVN

Slovenija

Uradni list Republike Slovenije 04.12.2018 - Uradnem listu RS ?t. 78 -PRAVILNIK o varovanju delavcev pred tveganji zaradi izpostavljenosti kemi?nim snovem pri delu

SWE

Sverige

Hygieniska gr?nsv?rden, AFS 2018:1

TLV-ACGIH

ACGIH 2019

PROPAN-2-OL

Threshold Limit Value

Legend:           (C) = CEILING ;  INHAL = Inhalable Fraction;  RESP = Respirable Fraction

8.2. Exposure controls

As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired through effective local aspiration.

When choosing personal protective equipment, ask your chemical substance supplier for advice.

Personal protective equipment must be CE marked, showing that it complies with applicable standards.

Provide an emergency shower with face and eye wash station.

Hand Protection                          Protect hands with category III work gloves (see standard EN 374). The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability.

The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the duration and type of use.

 Skin Protection                                               Wear category I professional long-sleeved overalls and safety footwear (see Regulation 2016/425 and standard EN ISO 20344). Wash body with soap and water after removing protective clothing.

 Consider the appropriateness of providing antistatic clothing in the case of working environments in which there is a risk of explosion.

 Eye Protection                                                Wear airtight protective goggles (see standard EN 166).

 Respiratory Protection                                     If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required.

Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the threshold values considered. The protection provided by masks is in any case limited.

If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.

 Environmental Exposure Controls                    The emissions generated by manufacturing processes, including those

generated by ventilation equipment, should be checked to ensure compliance with environmental standards.

 SECTION 9. Physical and chemical properties

 9.1. Information on basic physical and chemical properties

Appearance Transparent liquid

Colour Not available

Odour Characteristic, pleasant

Odour threshold Not available

pH Not available

Melting point / freezing point -88.3 °C

Initial boiling point 82.8 °C

Boiling range Not available

Flash point 11.7 °C

Evaporation rate Not available

Flammability (solid, gas) Not available

Lower inflammability limit Not available

Upper inflammability limit Not available

Lower explosive limit Not available

Upper explosive limit Not available

Vapour pressure 4.4 kPa (20 °C)

Density 785 kg/m3 (25 °C)

Relative density Not available

Solubility Completely soluble in water.

Partition coefficient: n-octanol/water Not available

Auto-ignition temperature 456°C

Decomposition temperature Not available

Explosive properties Not available

Oxidising properties Not available

 9.2. Other information                                   Information not available

 SECTION 10. Stability and reactivity 

 10.1. Reactivity                                              There are no particular risks of reaction with other substances in normal conditions of use. Decomposes under the effect of heat.

 10.2. Chemical stability                                 The product is stable in normal conditions of use and storage.

10.3. Possibility of hazardous reactions

The vapours may also form explosive mixtures with the air.

10.4. Conditions to avoid

Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition.

10.5. Incompatible materials

Information not available.

10.6. Hazardous decomposition products

In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released.

SECTION 11. Toxicological information

 11.1. Information on toxicological effects

 LD50 / LC50 values:

Acute Toxicity LC50 (Inhalation) LD50 (Oral) LD50 (Dermal)

 72,6 mg/l/4 hours rat 4710 mg/kg rat

12800 mg/kg rat

Skin Corrosion / Irritation Serious Eye Damage / Irritation Respiratory or Skin Sensitisation Germ Cell Mutagenicity Carcinogenicity

Does not meet the classification criteria for this hazard class Causes serious eye irritation

Does not meet the classification criteria for this hazard class Does not meet the classification criteria for this hazard class

Reproductive Toxicity STOT - Single Exposure STOT - Repeated Exposure Aspiration Hazard

Does not meet the classification criteria for this hazard class Does not meet the classification criteria for this hazard class May cause drowsiness or dizziness

Does not meet the classification criteria for this hazard class Does not meet the classification criteria for this hazard class

SECTION 12. Ecological information

 Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or contaminate soil or vegetation.

 12.1. Toxicity                                                 Information not available

 12.2. Persistence and degradability

PROPAN-2-OL                                               Rapidly degradable

 12.3. Bioaccumulative potential

PROPAN-2-OL

Partition coefficient: n-octanol/water                 0,05

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

Information not available.

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.

12.6. Other adverse effects

Information not available

SECTION 13. Disposal considerations

13.1. Waste treatment methods

Contaminated Packaging

Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations.

Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.

Waste transportation may be subject to ADR restrictions.

Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

SECTION 14. Transport information

 14.1. UN number

ADR / RID, IMDG, IATA:                                  1219

 14.2. UN proper shipping name

ADR / RID:                                                     ISOPROPANOL (ISOPROPYL ALCOHOL)

IMDG:                                                            ISOPROPANOL (ISOPROPYL ALCOHOL)

IATA:                                                             ISOPROPANOL (ISOPROPYL ALCOHOL)

Isopropanol

14.3. Transport hazard class(es)

ADR / RID: IMDG: IATA:

14.4. Packing group

Class: 3

Class: 3

Class: 3

Label: 3

Label: 3

Label: 3

ADR / RID, IMDG, IATA:

II

14.5. Environmental hazards

ADR / RID: IMDG:

No No

IATA:

No

14.6. Special precautions for user

ADR / RID:                                                     HIN – Kemler: 33 Limited Quantities: 1 L Tunnel restriction code: (D/E) Special Provision: -

IMDG:                                                            EMS: F-E, S-D Limited Quantities: 1 L

IATA:                                                             Cargo: -          Maximum quantity: 60 L Packaging instructions: 364 Pass.: -                       Maximum quantity: 5 L  Packaging instructions: 353 Special Instructions: A180

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

Information not relevant.

SECTION 15. Regulatory information

 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

 Seveso Category-Directive 2012/18/EC:           P5c

 Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006

Product           Point   3 - 40

Substances in Candidate List (Art. 59 REACH)

On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%.

Substances subject to authorisation (Annex XIV REACH)

None

Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012:

None Substances subject to the Rotterdam Convention:

None

Substances subject to the Stockholm Convention:

None

Healthcare controls:

Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks related to the workers' health and safety are modest and that the 98/24/EC directive is respected.

Isopropanol

German regulation on the classification of substances hazardous to water (AwSV, vom 18. April 2017)

WGK 1: Low hazard to waters Substance listed in Annex 2

15.2. Chemical safety assessment                A  chemical  safety  assessment  has  not  been  performed  for   the

preparation/for the substances indicated in section 3.

SECTION 16. Other information

 Information Source:                                         This Safety Data Sheet has been prepared based on provided information by supplier/manufacturer of this product and according to regulation EC No 2015/830 (REACH Annex II).

 Text of hazard (H) indications mentioned in section 2-3 of the sheet:

Flam. Liq. 2                 Flammable liquid, category 2

Eye Irrit. 2                   Eye irritation, category 2

STOT SE 3                 Specific target organ toxicity - single exposure,

category 3

H225                           Highly flammable liquid and vapour.

H319                           Causes serious eye irritation.

H336                           May cause drowsiness or dizziness.

 LEGEND:                                                       - ADR: European Agreement concerning the carriage of Dangerous goods by Road

- CAS NUMBER: Chemical Abstract Service Number

- CE50: Effective concentration (required to induce a 50% effect)

-    CE NUMBER: Identifier in ESIS (European archive of existing substances)

- CLP: EC Regulation 1272/2008

- DNEL: Derived No Effect Level

- EmS: Emergency Schedule

-   GHS: Globally Harmonized System of classification and labeling of chemicals

-  IATA DGR: International Air Transport Association Dangerous Goods Regulation

- IC50: Immobilization Concentration 50%

- IMDG: International Maritime Code for dangerous goods

- IMO: International Maritime Organization

- INDEX NUMBER: Identifier in Annex VI of CLP

- LC50: Lethal Concentration 50%

- LD50: Lethal dose 50%

- OEL: Occupational Exposure Level

- PBT: Persistent bioaccumulative and toxic as REACH Regulation

- PEC: Predicted environmental Concentration

- PEL: Predicted exposure level

- PNEC: Predicted no effect concentration

- REACH: EC Regulation 1907/2006

- RID: Regulation concerning the international transport of dangerous goods by train

- TLV: Threshold Limit Value

-  TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.

- TWA STEL: Short-term exposure limit

- TWA: Time-weighted average exposure limit

- VOC: Volatile organic Compounds

Isopropanol

-    vPvB: Very Persistent and very Bioaccumulative as for REACH Regulation

- WGK: Water hazard classes (German).

GENERAL BIBLIOGRAPHY

1. Regulation (EC) 1907/2006 (REACH) of the European Parliament

2. Regulation (EC) 1272/2008 (CLP) of the European Parliament

3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament

4. Regulation (EU) 2015/830 of the European Parliament

5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament

6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament

7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament

8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament

9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament

10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament

11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament

12. Regulation (EU) 2016/1179 (IX Atp. CLP)

13. Regulation (EU) 2017/776 (X Atp. CLP)

14. Regulation (EU) 2018/669 (XI Atp. CLP)

15. Regulation (EU) 2018/1480 (XIII Atp. CLP)

16. Regulation (EU) 2019/521 (XII Atp. CLP)

- The Merck Index. - 10th Edition

- Handling Chemical Safety

- INRS - Fiche Toxicologique (toxicological sheet)

- Patty - Industrial Hygiene and Toxicology

- N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition

- IFA GESTIS website

- ECHA website

-  Database of SDS models for chemicals – Ministry of Health and ISS (Istituto Superiore di Sanità) – Italy

Note for users:

The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product.

This document must not be regarded as a guarantee on any specific product property.

The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses.

Provide appointed staff with adequate training on how to use chemical products.

Product`s classification is based on the calculation methods set out in Annex I of the CLP Regulation, unless otherwise indicated in sections 11 and 12.

The data for evaluation of chemical-physical properties are reported in section 9.