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Nanoparticles often undergo thermally driven phase transitions and shape shifting spatial transformation resulting in a thermodynamically stable structures at that temperature. In case of crystalline nanoparticles, these transformations are usually anisotropic, meaning that they are surface dependent. This surface dependency of anisotropic phase transitions is attributed to the work function, surface energy and chemical potential of different crystal facets. When heated, these structures become unstable and begin to transform to an isotropic structure with high thermodynamic stability at a large range of temperature. Investigating these structural phase transitions at atomic scale may provide why some catalysts work terribly at high temperatures and why some catalysts fail to reactivate by thermal treatment. Researchers from Institute for basic science (IBS) have used environmental transmission electron microscopy (ETEM) to observe these structural transformations and geometric shape shifts in gold nanoparticles at atomic scale using phase-contrast microscopy. They studied two types of gold nanoparticles, gold nanorods and triangular gold nanoplates. Above 180°C at 1 mbar O?, surface encapsulating thiol ligands underwent surface desorption exposing the gold surfaces to the oxygen environment. In absence of any surface stabilizing ligands, surfaces atoms started to diffuse around transforming the gold nanoparticles to more thermodynamically stable structures. Nanorods were found to transform to nanoellipsoids whereas nanotriangles were found to transform to nanohexagons through the truncation of their vertices. However, the mechanisms of surface atom diffusion are different in these two cases. In case of nanorods, indiscriminate surface migration of vertex atoms to the sides was found to be driven by the formation of multiple intermediate high-index facets; on the other hand, selective layer-by-layer migration of vertex atoms to the triangular faces was found to have occurred in case of nanotriangles until a hexagonal shape is attained. The thermodynamic driving force here is the minimization of the low-coordinated gold surface atoms that anticipates the final spherical shape of the particles. The triangular geometry of the nanotriangles allowed the {111} surfaces on all faces remain intact during the transition to hexagonal geometry. ETEM experiments were conducted on an aberration-corrected Thermo Fisher Scientific Titan ETEM G2 operated at 300?keV and equipped with a Gatan Inc. UltraScan 1000XP CCD detector. In-situ heating inside the microscope was conducted with a Protochips Fusion in-situ heating TEM holder. Video description is in the comments. Read the interesting findings published in the Journal of Physical Chemistry C. https://lnkd.in/dPHrTx2C #phasetreansitions #surfaceatomdiffusion #phasecontrast #insituTEM #ETEM #Fusion #UltraScan1000XP #electronmicroscopy