To demonstrate the distinction between built-in and custom data structures, let's consider a few examples in Python. Suppose you want to store and process data about students and their grades. You may use a list of tuples, where each tuple includes the student's name and grade. This is a pre-existing data structure that is easy to create and access, but it may not be ideal for sorting, searching, or editing the data. Alternatively, you can employ a dictionary, with the keys as the student's names and values as their grades. This is another built-in data structure that is simple to create and access, allowing for rapid lookup and update of the data, but it may not maintain the order of the data or enable duplicate keys. Lastly, you can use a custom class, where each instance symbolizes a student with attributes for name and grade. This is a custom data structure that is more complicated to create and test, yet it gives you increased control and flexibility over the data and its behavior, plus it can be extended or modified as needed. Depending on your needs and preferences, you can select the data structure that best suits you, or even combine them in different ways. For instance, you can use a list of custom class instances, or a dictionary of custom class instances, or a custom class that contains a list or a dictionary as an attribute.