Hash tables are one of the most secure data structures for storing PCI in payment systems, for several reasons. First, hash tables can use encryption to store the values, making them unreadable without the key. Second, hash tables can use hashing to store the keys, making them irreversible without the hash function. Hashing is a process of transforming data into a fixed-length output, using a mathematical function. Hashing ensures that different keys produce different outputs, and that the same key always produces the same output. However, hashing is a one-way operation, meaning that it is impossible to recover the original data from the output. Therefore, hashing protects the keys from being exposed or guessed. Third, hash tables can use salt to enhance the security of hashing. Salt is a random data that is added to the data before hashing, making the output more unique and unpredictable. Salt prevents attackers from using pre-computed tables or dictionaries to crack the hashes.